Log In   |   Sign up

New User Registration

Article / Abstract Submission
Register here
Press Release Submission
Register here
coolingZONE Supplier
Register here

Existing User

            Forgot your password
John O | October 2018

Researchers create self-healing ion gels that could be the future of flexible electronics

By Josh Perry, Editor


Researchers from Yokohama National University and the University of Tokyo in Japan have developed a new ion gel that has enhanced toughness and self-heals at ambient temperatures without an external trigger, which they believe could be the future building block of flexible electronics.


The ion gel exhibits fast self-healing ability at room temperature by reforming hydrogen bonds at the damaged surface. The fracture stress of the ion gel after healing 3 h is comparable to that of the pristine ion gel. (Yokohama National University)


According to a report from the universities, ion gels have become a popular topic of study because they do not evaporate at room temperature, have high thermal stability, and high ionic conductivity. This new gel has multiple hydrogen bonds, which improves the material’s toughness.


The ion gel is filled with salts in liquid form (ionic liquids) and was created using a diblock copolymer, which is the combination of a material that is repelled by ionic liquids and a second that bonds with hydrogen.


“The combination of the liquid salts and the diblock copolymer material resulted in a final micellar structure that is responsible for all of the material's desirable qualities,” the report explained. “The block that is repelled by ionic liquids makes up the core, while the outside is composed of chains that interact with one another via multiple hydrogen bonds.”


Because hydrogen bonding is reversible, the material is self-healing and can be repaired in only a few hours. The researchers found that the healing process did not alter the gel’s mechanical or electrochemical properties.


The research was recently published in Advanced Materials. The abstract stated:


“Ion gels, composed of macromolecular networks filled by ionic liquids (ILs), are promising candidate soft solid electrolytes for use in wearable/flexible electronic devices. In this context, the introduction of a self?healing function would significantly improve the long?term durability of ion gels subject to mechanical loading. Nevertheless, compared to hydrogels and organogels, the self?healing of ion gels has barely investigated been because of there being insufficient understanding of the interactions between polymers and ILs.


“Herein, a new class of supramolecular micellar ion gel composed of a diblock copolymer and a hydrophobic IL, which exhibits self?healing at room temperature, is presented. The diblock copolymer has an IL?phobic block and a hydrogen?bonding block with hydrogen?bond?accepting and donating units.


“By combining the IL and the diblock copolymer, micellar ion gels are prepared in which the IL phobic blocks form a jammed micelle core, whereas coronal chains interact with each other via multiple hydrogen bonds.


“These hydrogen bonds between the coronal chains in the IL endow the ion gel with a high level of mechanical strength as well as rapid self?healing at room temperature without the need for any external stimuli such as light or elevated temperatures.”

Choose category and click GO to search for thermal solutions


Subscribe to Qpedia

a subscription to qpedia monthly thermal magazine from the media partner advanced thermal solutions, inc. (ats)  will give you the most comprehensive and up-to-date source of information about the thermal management of electronics


Submit Article

if you have a technical article, and would like it to be published on coolingzone
please send your article in word format to articles@coolingzone.com or upload it here

Subscribe to coolingZONE

Submit Press Release

if you have a press release and would like it to be published on coolingzone please upload your pr  here

Member Login

Supplier's Directory

Search coolingZONE's Supplier Directory
become a coolingzone supplier

list your company in the coolingzone supplier directory

suppliers log in

Media Partner, Qpedia


Heat Transfer Calculators